Cadmium is one of the most widely distributed and toxic pollutants in nature, and the remediation of Cd pollution is still a difficult and serious task. In this paper, the biochar derived from walnut shells and sunflower seed shells were prepared at 700°C. The two kinds of biochar were characterized by SEM and FTIR, and the effects of pH, adsorption time, initial concentration on the adsorption of Cd2+ in aqueous solution were investigated. The adsorption kinetics were studied and the experimental data was also fitted with the isotherm equilibrium models. The results showed that the adsorption amount of Cd2+ increased with the pH when the solution pH was between 2 and 7. The maximum adsorption amount of Cd in water was up to 12.94 mg•g-1 and 21.11 mg•g-1 for BWS and BSS. The adsorption kinetics of Cd2+ on the BWS and BSS followed pseudo-second-order kinetics. The Langmuir adsorption isotherm was used to describe the adsorption equilibrium process isotherms. Thermodynamic studies showed that the adsorption reaction was spontaneous, endothermic and entropy increasing. The analysis of microstructural characteristics indicated that complexation and ion exchange are the main mechanisms of cadmium adsorption on the two kinds of biochar. And the surface of the BSS contained a large number of functional groups. Compared with the BSS exhibited better Cd2+ adsorption capacity. The results of this research are important for the resourceful use of waste and the purification of heavy metals in water.
| Published in | International Journal of Environmental Protection and Policy (Volume 10, Issue 3) |
| DOI | 10.11648/j.ijepp.20221003.14 |
| Page(s) | 67-72 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2022. Published by Science Publishing Group |
Biochar, Walnut Shell, Sunflower Seed Shell, Cd2+, Adsorption
| [1] | Tao Q, Chen Y X, Zhao J W, et al. Enhanced Cd removal from aqueous solution by biologically modified biochar derived from digestion residue of corn straw silage [J]. Science of the Total Environment, 2019, 674: 213-222. |
| [2] | Cai R Z, Tan C Y, Cao X Y, et al. Physicochemical properties and adsorption effect of cadmium on biochar from teak peel [J]. Journal of Natural Sciences, Hunan Normal University, 2022, 45 (01): 57-66. |
| [3] | Liu S J, Liu Y G, Tan X F, et al. The effect of several activated biochar on Cd immobilization and microbial community composition during in-situ remediation of heavy metal contaminated sediment [J]. Chemosphere, 2018, 208: 655-664. |
| [4] | Zhou J H, Song Q Y, Luo W, et al. Removal of Hg (II) and Cd (II) from wastewater by biochar/fly ash [J]. Environmental Science and Technology, 2021, 44 (S2): 245-252. |
| [5] | Li B, Yang L, Wang C Q, et al. Adsorption of Cd (II) from aqueous solutions by rape straw biochar derived from different modification processes [J]. Chemosphere, 2017, 175: 332-340. |
| [6] | Hu X Y, Chen Y J, Zhang S S, et al. Removal of Cd from water bodies by magnetic corn stover biochar and recycling [J]. Journal of Agricultural Engineering, 2018, 34 (19): 208-218. |
| [7] | Cao J H, Liu L X, Huang Y J, et al. Effect of feedstock type and pyrolysis temperature on the adsorption of Cd (II) by biochar [J]. Chemical Progress, 2019, 38 (09): 4183-4190. |
| [8] | Sheng X C, Sima X F, Meng Y, et al. Characterization of Cd adsorption by two types of straw biochar [J]. Journal of Anhui Agricultural University, 2021, 48 (05): 829-833. |
| [9] | Wang R Y. Current situation and development prospect of sunflower oil industry in China [J]. China Oil and Fats, 2020, 45 (3): 1-3. |
| [10] | Zhang Y L, Yuan S J, Wang X J, et al. Analysis and consideration of walnut processing industry based on the development strategy of Chinese walnuts [J]. Journal of Agricultural Engineering, 2015, 31 (21): 1-8. |
| [11] | Guo H Y, HeC X. Physicochemical properties of four biochar and their adsorption performance on methylene blue [J]. Materials Development and Applications, 2019, 34 (2): 113-119. |
| [12] | Yang H X, Xu Y, Fang X, et al. Analysis of elemental composition cellulose content and crystallinity of common nut shells [J]. Anhui Agricultural Science, 2016, 44 (17): 21-23, 129. |
| [13] | Martinez M L, Torres M M, Guzman C A, et al. Preparation and characteristics of activated carbon from olive stones and walnut shells [J]. Industrial Crops and Products, 2006, 23: 23-28. |
| [14] | Bandara T, Xu J M, Potter L D, et al. Mechanisms for the removal of Cd (II) and Cu (II) from aqueous solution and mine water by biochars derived from agricultural wastes [J]. Chemosphere, 2020, 254: 1-10. |
| [15] | Chen Q, Zheng J W, Zheng L C, et al. Classical theory and electron-scale view of exceptional Cd (II) adsorption onto mesoporous cellulose biochar via experimental analysis coupled with DFT calculations [J]. Chemical Engineering Journal, 2018, 350: 1000-1009. |
| [16] | Zhao Y F, Zhang B, Zhang X, et al. Preparation of highly ordered cubic naa zeolite from halloysite mineral for adsorption of ammonium ions [J]. Journal of Hazardous Materials, 2010, 178 (1-3): 658-664. |
| [17] | Niu Y Z, Qu R J, Sun C M, et al. Adsorption of Pb (II) from aqueous solution by silicagel supported hyperbranched polyamidoamine dendrimers [J]. Journal of Hazardous Materials, 2013, 244-245: 276-286. |
| [18] | Fan S S, Li X, Hu K, et al. Kinetics and thermodynamics of heavy metal Cd adsorption by sludge-based biochar [J]. Journal of Environmental Engineering, 2016, 10 (10): 5971-5977. |
| [19] | Cao J H, Liu LQ, Huang Y J, et al. Effect of feedstock type and pyrolysis temperature on the adsorption of Cd (II) by biochar [J]. Chemical Progress, 2019, 38 (9): 4183-4190. |
| [20] | Ma F F, Zhao B W, Diao J R. Study on the adsorption characteristics of wheat straw biochar on Cd (II) in water [J]. China Environmental Science, 2017, 37 (2): 551-559. |
| [21] | Xu N N, Lin D S, Xu Y M, et al. Adsorption characteristics and influencing factors of Cd (II) by corn straw biochar [J]. China Environmental Science, 2017, 37 (2): 551-559. |
APA Style
Ye Jinsha, Luo Xin, Liu Ruisen. (2022). Adsorption Performance of Two Kinds of Biochar for Cd2+ in Water. International Journal of Environmental Protection and Policy, 10(3), 67-72. https://doi.org/10.11648/j.ijepp.20221003.14
ACS Style
Ye Jinsha; Luo Xin; Liu Ruisen. Adsorption Performance of Two Kinds of Biochar for Cd2+ in Water. Int. J. Environ. Prot. Policy 2022, 10(3), 67-72. doi: 10.11648/j.ijepp.20221003.14
AMA Style
Ye Jinsha, Luo Xin, Liu Ruisen. Adsorption Performance of Two Kinds of Biochar for Cd2+ in Water. Int J Environ Prot Policy. 2022;10(3):67-72. doi: 10.11648/j.ijepp.20221003.14
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Download@article{10.11648/j.ijepp.20221003.14,
author = {Ye Jinsha and Luo Xin and Liu Ruisen},
title = {Adsorption Performance of Two Kinds of Biochar for Cd2+ in Water},
journal = {International Journal of Environmental Protection and Policy},
volume = {10},
number = {3},
pages = {67-72},
doi = {10.11648/j.ijepp.20221003.14},
url = {https://doi.org/10.11648/j.ijepp.20221003.14},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepp.20221003.14},
abstract = {Cadmium is one of the most widely distributed and toxic pollutants in nature, and the remediation of Cd pollution is still a difficult and serious task. In this paper, the biochar derived from walnut shells and sunflower seed shells were prepared at 700°C. The two kinds of biochar were characterized by SEM and FTIR, and the effects of pH, adsorption time, initial concentration on the adsorption of Cd2+ in aqueous solution were investigated. The adsorption kinetics were studied and the experimental data was also fitted with the isotherm equilibrium models. The results showed that the adsorption amount of Cd2+ increased with the pH when the solution pH was between 2 and 7. The maximum adsorption amount of Cd in water was up to 12.94 mg•g-1 and 21.11 mg•g-1 for BWS and BSS. The adsorption kinetics of Cd2+ on the BWS and BSS followed pseudo-second-order kinetics. The Langmuir adsorption isotherm was used to describe the adsorption equilibrium process isotherms. Thermodynamic studies showed that the adsorption reaction was spontaneous, endothermic and entropy increasing. The analysis of microstructural characteristics indicated that complexation and ion exchange are the main mechanisms of cadmium adsorption on the two kinds of biochar. And the surface of the BSS contained a large number of functional groups. Compared with the BSS exhibited better Cd2+ adsorption capacity. The results of this research are important for the resourceful use of waste and the purification of heavy metals in water.},
year = {2022}
}
TY - JOUR T1 - Adsorption Performance of Two Kinds of Biochar for Cd2+ in Water AU - Ye Jinsha AU - Luo Xin AU - Liu Ruisen Y1 - 2022/06/01 PY - 2022 N1 - https://doi.org/10.11648/j.ijepp.20221003.14 DO - 10.11648/j.ijepp.20221003.14 T2 - International Journal of Environmental Protection and Policy JF - International Journal of Environmental Protection and Policy JO - International Journal of Environmental Protection and Policy SP - 67 EP - 72 PB - Science Publishing Group SN - 2330-7536 UR - https://doi.org/10.11648/j.ijepp.20221003.14 AB - Cadmium is one of the most widely distributed and toxic pollutants in nature, and the remediation of Cd pollution is still a difficult and serious task. In this paper, the biochar derived from walnut shells and sunflower seed shells were prepared at 700°C. The two kinds of biochar were characterized by SEM and FTIR, and the effects of pH, adsorption time, initial concentration on the adsorption of Cd2+ in aqueous solution were investigated. The adsorption kinetics were studied and the experimental data was also fitted with the isotherm equilibrium models. The results showed that the adsorption amount of Cd2+ increased with the pH when the solution pH was between 2 and 7. The maximum adsorption amount of Cd in water was up to 12.94 mg•g-1 and 21.11 mg•g-1 for BWS and BSS. The adsorption kinetics of Cd2+ on the BWS and BSS followed pseudo-second-order kinetics. The Langmuir adsorption isotherm was used to describe the adsorption equilibrium process isotherms. Thermodynamic studies showed that the adsorption reaction was spontaneous, endothermic and entropy increasing. The analysis of microstructural characteristics indicated that complexation and ion exchange are the main mechanisms of cadmium adsorption on the two kinds of biochar. And the surface of the BSS contained a large number of functional groups. Compared with the BSS exhibited better Cd2+ adsorption capacity. The results of this research are important for the resourceful use of waste and the purification of heavy metals in water. VL - 10 IS - 3 ER -
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